As a comfortable possibility: the inside-windowsill where in all rule also the edge of the window frame runs in parallel to the position of the sundial-wall and the window panel as a vertical shadow of sun can be used.
Before with spirit level examine!
2. Working steps (Compares foto):
The work is to be explained with care, because the exactness of the later calculation depends on it!
Paper long edge in parallel to the sundial wall (mostly it is enough the paper in the window frame to put in) straighten and with adhesive tape fasten.
Window panel open and turn thus that the shade fells on the paper.
This shade with two points mark (and the clock time of this moment notice themselves) and afterwards to a straight line to connect and measure the angle.
Make a good sketch and keep it for later calculation.
To the control and to the necessary security the second measurement still is take some time around midday.